Algebraic structures of N = (4; 4) and N = (8; 8) supersymmetric (SUSY) twodimensional sigma models on Lie groups (in general) and SUSY Wess-Zumino-Witten(WZW) models (as special) are obtained. For SUSY WZW models, these algebraicstructures are reduced to Lie bialgebraic structures as for the N = (2; 2) SUSYWZW case; with the difference that there is a one 2-cocycle for the N = (4; 4)case and there are two 2-cocycles for the N = (8; 8) case. In general, we showthat N = (8; 8) SUSY structure on Lie algebra must be constructed from two N =(4; 4) SUSY structures and in special there must be two 2-cocycles for Manintriples (one 2-cocycle for each of the N = (4; 4) structures). Some examplesare investigated. In this way, a calculational method for classifying the N =(4; 4) and N = (8; 8) structures on Lie algebras and Lie groups are obtained.
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